I think the replacement No.2 is running efficiently where as the others are worn to varying degrees.Replaced injector #2 and programmed it using MES. Did the test again on cold engine.
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Injectors 1 and 3 returned ~35ml
Injector 2 (new) returned ~15ml
Injector 4 returned ~50ml
Does the new injector (2) return correct amount? Shouldn’t it return around the same amount as 1 and 3 injectors?
Still getting white smoke and knocking. Thinking of replacing injector 4, but the injectors 0445110418 are now out of stock and discontinued. It appears it was replaced by part number 0445110520 but I read on forum that it cannot be programmed using MES?
Injectors need a little "leak off" to lubricate the moving parts of the injectors, unlike petrol injectors which are made of different materials as petrol is not self lubricating. Also much lower operating pressure requirements.
Re your early comments on no. 5 posting "What is not expected, is white smoke on cold start, which couldn’t be regen, since it doesn’t regen when engine is cold."
I have had a DPF issue on a 2012 Citroen C3 Picasso 1.6 diesel which was badly blocked and it definitely chucked out choking clouds of white fumes from stone cold, although it never cleared as your engine does and didn't smell like diesel fumes. I had to remove and clean the DPF , then tell the Computer that a new DPF had been fitted, after that it was fine for 4 years until I then fitted a new DPF.