Both basic front to rear torque systems perform similarly, though one is mechanical and the other electronically control.
The viscous coupling on the Climbing is basically two shafts joined together by plates in a tube filled with thick fluid.
Every other plate lock into one shaft, the others in between lock into the other shaft. (very similar to a motorbikes wet clutch).
With no pressure on the plates, they slip past one another and no torque transmits from one shaft to the other.
When it all starts slipping the thick fluid drags on the plates, thus sending torque through it, the more slip the more drag on the plates, the more torque.
It's totally automatic and self regulating.
The later models with the electronic system uses a power transfer unit on the back of the gearbox with an electromagnetic actuator to engage and disengage a dog clutch (inter locking cogs) to transmit power to the rear axle.
The system is controlled by the powertrain ECU and uses sensors to detect when and how much power is needed to the rear.
Now where they differ is with this electronic system, it's easier to over ride and lock the transmission 50/50 than it is to lock a viscous coupling, it's just a matter of signalling the electromagnetic actuator.
(this locking is part, but not all of what the ELD system)
Where as to pre lock the viscous, there needs to be some way of altering the state of the fluid in the system (pump) or some other way of locking the two shafts together.
I believe due to weight/cost/reliability Fiat did not include a front to back lock on this viscous system.
So both can alter power centrally between front and rear axles, though only the later electronic system can pre lock the front to back transfer of torque.
Due to the other systems these later models have, like the stability control (ESC) along with the ABS, they can also "lock" the diffs on each axle (side to side), though it's not a true lock, just the effects are similar.
By using the ESC it can detect a slipping wheel and using the ESC & ABS systems it can grab that brake (as it would on the road, just now it's works with smaller amounts of wheel speed differences), thus sending that axles torque to the other wheel, which normally due to the open diff would not have received any torque (it would have all spun away on the slipping wheel).
This is the other part of the ELD system, by pressing the button you pre lock the front to back diff and alter the ESC system it already has to grab brakes on slipping wheels.
Really it just using the systems it already has, mainly the ESC, but by pressing the button it's using a different set of perimeters.
Now the later Cross model takes this electronic system a bit further.
Instead of the ELD being on or off, the system has different settings to allow for different conditions.
So for mud it might lock front to back 50/50 and jack the "mock" front and rear diff locks reaction times right up as it knows it's going to be searching for grip, for gravel it might back the system off slightly as it's a bit loose, but grip is there somewhere. Hill decent might jack up the ABS response and again alter the front to back power split to a more favourable setting.
As I said before, without all this electronic "locking", it's still very capable on the slippy stuff in normal mode.
I just sit there and blaze away through, it's worked so far!