yes the mark on the crankshaft pulley is fine to use for piston 1 TDC. then you fit the cam locking tools by removing a bearing cap on each camshaft and fitting the locking tool in its place, one on each camshaft. if you dont know how to use cam locking tools, read haynes, it is very very easy, and fool proof. it will guarantee that the inlet and exhaust camshafts are in perfect position, you cant get it wrong (unless you remove the wrong bearing cap on either camshaft, but that requires complete stupidity).
if you want to get piston 1 TDC more accurately than you can using the mark (not neccessary imo) then you can stick a rod in the piston 1 spark plug hole and watch it rising as the crankshaft pulley is turned. when the mark on the pulley is in position, you should have noticed that the rod stops rising. stop turning the crankshaft pulley as soon as the rod stops riing, the check that the mark on the pulley lines up with the indent on the sump. then select 5th gear to lock the crankshaft. easy peasy
if you turn the crankshaft pulley or either cam pulley more than a small amount, valve to piston contact will occur, and that can easily mean valve damage. if you turn everything very slowly and carefully you will spot contact (hear and feel it) before you damage any valves.