You've gone for a 540cc conversion? I considered that. There are 3 ways you could go.
First, and best, is to take your car to a dyno. They'll measure the air fuel ratio at different throttle openings and different speeds. They'll tell you it's rich in one place and lean in another and will take a guess at what size jets you need. If you have the jets with you, swap them out and do another run to confirm.
Second is to find someone who's already done that and use the same jets as them.
Third is what I did, but I don't recommend it. I tried loads of different combinations, tested to see if they seamed lean or rich, and tested the top speed at a fixed point on the dual carriageway. Standard jetting for my 594cc engine was too rich at the top. Standard jetting for the 652 was too lean at the bottom. I found the setting half way between the two works very well, and that one main jet size either side gave a lower top speed.